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Critical Surface Tension and Contact Angle with Water for Various Polymers |
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| ID #(1) ↓↑ | Polymer Name(2) ↓↑ | CAS #(3) ↓↑ | γS(4) ↓↑ | Contact Angle(5) ↓↑ |
| 1 | 9003-56-9 | 38.5 | 80.9 | |
| 2 | - | 44.5 | 76.3 | |
| 3 | 25067-11-2 | 19.1 | 108.5 | |
| 4 | 630-06-8 | 20.6 | 108.5 | |
| 5 | 25038-54-4 | 43.9 | 62.6 | |
| 6 | 32131-17-2 | 42.2 | 68.3 | |
| 7 | - | 43 | 70 | |
| 8 | - | 34 | 86 | |
| 9 | - | 34 | 86 | |
| 10 | - | 32 | 94 | |
| 11 | 25587-80-8 | 35.6 | 82 | |
| 12 | 24937-16-4 | 37.1 | 72.4 | |
| 13 | 8002-74-2 | 24.8 | 108.9 | |
| 14 | 9003-17-2 | 29.3 | 96 | |
| 15 | 25608-33-7 | 29.8 | 91 | |
| 16 | 25189-00-9 | 18.1 | 108.1 | |
| 17 | 24936-68-3 | 44 | 82 | |
| 18 | 9002-83-9 | 30.8 | 99.3 | |
| 19 | 9016-00-6 | 20.1 | 107.2 | |
| 20 | 9002-88-4 | 31.6 | 96 | |
| 21 | 25322-68-3 | 43 | 63 | |
| 22 | 25038-59-9 | 39 | 72.5 | |
| 23 | - | 16.9 | 112 | |
| 24 | 9003-27-4 | 27 | 112.1 | |
| 25 | 9011-14-7 | 37.5 | 70.9 | |
| 26 | 24969-26-4 | 37 | 76.8 | |
| 27 | 26125-40-6 | 38 | 80.3 | |
| 28 | (a) | 30.5 | 102.1 | |
| 29 | 9003-53-6 | 34 | 87.4 | |
| 30 | 25135-51-7 | 42.1 | 70.5 | |
| 31 | 9002-84-0 | 19.4 | 109.2 | |
| 32 | 24980-67-4 | 26.5 | 92 | |
| 33 | 9003-20-7 | 35.3 | 60.6 | |
| 34 | 25213-24-5 | 37 | 51 | |
| 35 | 9002-86-2 | 37.9 | 85.6 | |
| 36 | 24981-14-4 | 32.7 | 84.5 | |
| 37 | 9002-85-1 | 40.2 | 80 | |
| 38 | 24937-79-9 | 31.6 | 89 | |
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(1) ID numbers identify polymer data points
in critical surface tension vs. contact angle chart. (2) Names which are most widely used to describe
the material or family of materials (e.g., polyurethanes and epoxies) at hand
are preferred here. Commonly used acronyms and synonyms are also shown. (3) CAS (Chemical Abstract Series) numbers are
shown where available. In a number of instances, more than one CAS number
is assigned to a given polymer in some cases the details and nuances
of these divergences are not at all clear. We have tried to reference the
CAS number which appears to have the widest use with reference to the solid
state properties of
the given polymer. (4) Critical surface tension in
mJ/m2 (equivalent to dynes/cm), generally determined by the Zisman
method (regression of the cosine of the contact angle), or by the wetting tension
method (using solutions of 2-ethoxyethanol and formamide,
per ASTM Std. D-2578). (5) Contact angle with water, in degrees. The arithmetic
mean of all equilibrium (Young's) and advancing contact angle measurements
is shown. Generally, the equilibrium angle is similar to, but slightly lower
than, the advancing angle;
the balance of equilibrium vs. advancing contact angles from which this summary
is drawn may have some effect on
the average as shown for some polymers.
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